Table III. Mechanical properties of transmissive optical materials
 Material  Symbol Strength
Fa
Fracture
Toughness
Hardness
(Knoop)
Density
D
 Comments


MPa MPa·m½ kgf/mm2 g/cm3
Sodium chloride NaCl 2.4 (9.5) ? 18 2.16 cleaves
Potassium chloride KCl 2.2 (11) ? 17 1.98 least hygroscopic salt, cleaves
Potassium bromide KBr 1.1 ? 7 2.75 cleaves
Cesium bromide CsBr 8.3 ? 20 4.44 shock resistant, does not cleave
Cesium iodide CsI 2.7 (5.6) ? 20 4.53 shock resistant, deforms (cold flow)
             
Lithium fluoride LiF 11 ? 99 2.64 sensitive to thermal shock, cleaves
Magnesium fluoride MgF2 49 1.0 415 (575)  3.18 rugged, cleaves
Calcium fluoride CaF2 37 (54) 0.5 158 3.18 hard, fairly tough
Strontium fluoride SrF2 ~35 ? 154 4.28  
Barium fluoride BaF2 27 ? 82 4.88 sensitive to mechanical shock
             
Silver chloride AgCl 26 (<1) ? 10 5.56 deforms (cold flow)
Silver bromide AgBr ~30 (1.1) ? 7 6.47 deforms (cold flow)
Thallium bromochloride KRS-6 21 ? 39 7.19 deforms (cold flow), dust very toxic
Thallium bromoiodide KRS-5 26 ? 40 7.37 deforms (cold flow), dust very toxic
             
Magnesium oxide MgO 27 ? 692 3.58 tough
Sapphire a Al2O3 448 (689) 3.0 1370 3.98 very hard, tough
Crystal quartz a SiO2 ~41 ? 820 2.65 brittle, inert, cleaves
Zirconia ZrO2 ? 2.0 ~1160 5.85  
             
Zinc sulfide ZnS 60 (103) 0.5 (0.8) 160 (250) 4.09 tough, dust allergenic
Zinc selenide ZnSe 55 0.33 120 5.27 fairly tough, dust allergenic
Cadmium sulfide CdS 28 ? 108 4.82 birefringent, dust toxic
Cadmium selenide CdSe ? ? ~70 5.67 brittle, birefringent, dust toxic
Cadmium telluride CdTe ~6 ? 56 5.85 very brittle, dust toxic, visually opaque
             
Diamond C 370 (8700) 2.0 8820 3.52 very hard & inert, cleaves
Silicon Si ~62 0.95 1150 2.33 very hard & inert, visually opaque
Germanium Ge ~49 0.66 780 5.33 very brittle, visually opaque
Gallium arsenide GaAs ~50 ? 721 5.32 dust toxic
             
Silica glasses vSiO2 ~35 0.8 461 2.20  
Borosilicate glasses BSCG ~35 ? ~500 2.35  
Fluorozirconate glass HMFG ~25 ? 225 4.33 sensitive to thermal shock
Arsenic trisulfide glass As2S3 ~8 ? 109 3.20 brittle, dust toxic
AMTIR-1 glass AMTIR ~18 ? 170 4.40 brittle, visually opaque, dust toxic
GASIR1 glass GASIR1 ~17 ? ? 4.40 visually opaque, dust toxic, moldable
GASIR2 glass GASIR2 ~18 ? 172 4.70 visually opaque, dust toxic, moldable
             
Poly-ethylene HDPE 27 ? ~9 (R60) 0.95 LDPE deforms, hardness only ~4 (R15)
Poly-methylpentene TPX ~24 ? ~8 (R60) 0.83 fairly rigid
Polyester PET ~98 ? ~13 (R110) 1.37 strong, e.g. stretched-film windows
Poly-tetrafluoroethylene PTFE ~22 ? ~7 (R58) 2.24 deforms (cold flow), visually opaque
Fluorinated EPC FEPC ~18 ? ~5 (R25) 2.15 deforms (cold flow)
Strength (Fa) is defined as the elastic limit or flexural apparent elastic limit.
Crystalline strength is often limited by brittleness & cleavage; higher effective strength can often be achieved by careful orientation & mounting.
Parenthetical Fa values for CaF2, NaCl, KCl, & ZnS are for polycrystalline materials.
Parenthetical Fa value for CsI is for work-hardened material.
Parenthetical Fa values for AgCl & AgBr are empirical "strengths" for long-term pressure applications where cold flow is the determining factor.
The low Fa value for diamond reflects its brittleness & easy cleavage; its parenthetical Fa value is achieved by careful orientation & mounting.
Fracture toughness measures the difficulty of propagating an incipient fracture.
Fracture toughness value for ZnS is for the crystalline material; the parenthetical value is for CVD material.
Parenthetical hardness values for MgF2 and ZnS are for hot-pressed materials (i.e., Irtran).
Knoop hardness values for plastic resins are rough estimates. Measured hardness values for plastic resins are in Rockwell "R" units.
These data were collected from a variety of sources, so this table probably contains errors. Use cautiously, and empirically verify critical values.
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